No provider of chat rooms guarantees "safety." Safety is your business. There are no rooms where you can divulge personal info without being at risk. Any chat room is "safe" if you use common sense and remember to trust no one in that environment. It's your responsibility to be smart.
Married women can aces safe chat rooms available in social community networks as yahoo provides. There you can debate on usual topics as children, housework and intimate related problems. Based on a high privacy it allows a user to keep part of the profile information secret and to reveal only some.